under a strain - traduzione in olandese
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under a strain - traduzione in olandese

TYPE OF STRAIN ENERGY IN ORGANIC CHEMISTRY
A-1,3-strain

under a strain      
in spanning
Down Under         
COLLOQUIALISM TO REFER TO AUSTRALIA AND NEW ZEALAND
Down under; Downunder; Down-under; Down-Under
bij de tegenvoeters, in Australië en Nieuw-Zeeland en omgeving
under a cloud         
WIKIMEDIA DISAMBIGUATION PAGE
Under A Cloud; Under a Cloud (disambiguation); Under a cloud
verdacht

Definizione

strain gauge
¦ noun a device for indicating the strain of a material or structure at the point of attachment.

Wikipedia

Allylic strain

Allylic strain (also known as A1,3 strain, 1,3-allylic strain, or A-strain) in organic chemistry is a type of strain energy resulting from the interaction between a substituent on one end of an olefin (a synonym for an alkene) with an allylic substituent on the other end. If the substituents (R and R') are large enough in size, they can sterically interfere with each other such that one conformer is greatly favored over the other. Allylic strain was first recognized in the literature in 1965 by Johnson and Malhotra. The authors were investigating cyclohexane conformations including endocyclic and exocylic double bonds when they noticed certain conformations were disfavored due to the geometry constraints caused by the double bond. Organic chemists capitalize on the rigidity resulting from allylic strain for use in asymmetric reactions.